加强环境监测的全过程质量管理

质量管理是环境监测赖以生存和发展的基础,目前,环境监测质管工作中“重结果、轻过程”的问题仍然普遍存在,加强全过程质量管理才能确保监测数据的准确性和可靠性,为实现环境资源的可持续利用提供强有力的技术支撑。文章叙述了环境监测质量管理的发展概况,引出全过程质量管理的概念,提出从提高全员质量意识、建立健全质量管理体系、实施全过程的质量保证、加大质控工作力度等几方面加强环境监测的全过程质量管理,从而提升环境监测机构整体质量管理水平。     

浅谈龙江县人为水土流失的防治对策

本文分析了龙江县水土流失的成因及危害,并提出了机关的防治对策,对今后的水土保养、合理开发有一定的借鉴作用.     

引水工程前后西湖流场的数值模拟研究

采用Delft 3D水动力学计算模型,对西湖西进工程前后的流场进行了模拟,计算结果与实测资料较为吻合,模型真实可靠.各种工况下的流场模拟结果表明在不考虑风场的情况下,各进出水口的流量和位置决定了西湖的流场结构,而流场结构决定了水体的推移扩散规律.总体上,南湖水体推移扩散效果最好,西里湖、外湖和岳湖次之,北里湖最差,基本不能被置换.西湖水体的置换效果主要取决于可被置换区域的面积和引水量,而可被置换区域大小主要取决于流场结构.因此,在引水量不变的前提下,优化西湖水体置换效果的根本途径就是调整进出水口位置和流量大小,以改变流场结构.     

风景区中影视拍摄的环境规制研究

影视剧组在风景区的拍摄活动,往往造成风景区的环境破坏。文章首先对风景区中影视拍摄所造成的破坏类型进行分析,然后从相关责任主体方面探讨造成该问题的原因,最后根据环境规制发展的趋势,提出风景区中影视拍摄的规制对策：政府部门的强制性规制和影视剧组的自愿性规制两者相结合。     

硝化抑制剂的加量对生化需氧量值影响的探讨

BOD作为衡量水体受有机污染程度的重要指标,其反映的可生化降解性是其他参数无法替代的。在5日生化培养时间内,硝化作用的耗氧量取决于是否存在足够数量的能进行此种氧化作用的微生物,许多二级生化处理的出水和受污染较久的水体中,往往含有大量硝化微生物,因此测定这种水样时应抑制其硝化反应。通过对特定水体硝化抑制剂添加与否及加量多少对BOD5测定结果的影响,分析并探讨抑制特定水体硝化过程的最佳条件。在严格质量控制的基础上,对特定行业和环境水体的实际样品进行硝化抑制剂添加与否和加量及时间培养曲线等对比实验,通过所得到的比对数据以化学需氧量值与BOD5之间关系为基准,对硝化抑制剂的加量进行了探究。     

Enantioselective separation and zebrafish embryo toxicity of insecticide beta-cypermethrin

Enantioselectivity of chiral pollutants is receiving growing concern due to the difference in toxicology and environment fate between enantiomers.In this study,enantiomers of insecticide beta-cypermethrin (beta-CP) were separated on selected chiral column by HPLC,and the toxicity of enantiomers was evaluated using the zebrafish embryo-larval assays.The enantiomers of beta-CP were baseline separated on Chiralcel OD and Chiralpak AD columns and detected by circular dichroism (CD) at 236 nm.Better separation could be achieved at lower temperature (e.g.,20°C) and with lower levels of polar modifiers.Pure enantiomers were obtained on Chiralcel OD.The CD spectra of enantiomers were recorded.By comparing the elution order with a previous similar study,the absolute configuration of beta-CP enantiomers was determined.The individual enantiomers were used in zebrafish embryo test,and the results showed that beta-CP enantioselectively induced yolk sac edema,pericardial edema and crooked body.The 1R-cis-αS and 1R-trans-αS enantiomers showed strong developmental toxicities at concentration of 0.1 mg/L,while the 1S-cis-αR and 1S-trans-αR induced no malformations at higher concentration (e.g.,0.3 mg/L).The results suggest that the enantioselective toxicological effects of beta-CP should be considered when evaluating its ecotoxicological effects.     

鼎鑫煤化有限公司焦化废水处理工程实践

介绍了河北涉县鼎鑫煤化有限公司的焦化废水处理工程,详细论述了该工程所采用的"隔油+气浮+生化处理+脱色混凝"处理工艺,分析了DO、pH及温度等因素对运行效果的影响,并对该工程运行后的综合效益进行了分析.运行结果显示:系统出水的COD、SS、NH3-N、挥发酚、氰化物、硫化物、石油类质量浓度分别为140,100,20,0...     

Formation and cytotoxicity of a new disinfection by-product (DBP) phenazine by chloramination of water containing diphenylamine

Disinfection by-products (DBPs) in drinking water have caused worldwide concern due to their potential carcinogenic effects. The formation of phenazine from diphenylamine (DPhA) chloramination was studied and its cytotoxicities for two human cancer cells were also investigated. Phenazine was detected synchronously with the consumption of DPhA by chloramination, which further confirmed that the new DBP phenazine can be produced along with N-nitrosodiphenylamine (NDPhA) from DPhA chloramination. The formation of phenazine had a maximum molar yield with solution pH increasing from 5.0 to 9.0, with phenazine as the main product for DPhA chloramination at lower pH, but higher pH favored the formation of NDPhA. Thus, solution pH is the key factor in controlling the formation of phenazine and NDPhA. Both the initial DPhA and chloramine concentrations did not show a significant effect on the molar yields of phenazine, although increasing the chloramine concentration could speed up the reaction rate of DPhA with chloramines. The cytotoxicity assays showed that phenazine had significant cell-specific toxicity towards T24 (bladder cancer cell lines) and HepG2 (hepatic tumor cell lines) cells with IC50 values of 0.50 and 2.04 mmol/L, respectively, and T24 cells being more sensitive to phenazine than HepG2 cells. The IC50 values of phenazine, DPhA, and NDPhA for T24 cells were of the same order of magnitude and the cytotoxicity of phenazine for T24 cells was slightly lower than that of NDPhA (IC50, 0.16 mmol/L), suggesting that phenazine in drinking water may have an adverse effect on human health.     

电力系统震后恢复过程及经济损失研究

本文通过专家咨询的方法,调查、分析、研究了我国电力系统的震后恢复过程,给出了电力系统主体部分、分布部分、服务部分震后功能损失的30％、60％和100％得到恢复的时间,计算了损失工作日数和间接经济损失,研究表明,震后恢复时间和损失工作日数均随地震烈度呈对数上升趋势,并且主体部分的震后恢复时间最长,损失工作日数最多,分布部分次之,服务部分的震后恢复时间最短,损失工作日数最少。本文还讨论了电力系统经济损失的分类和计算方法。